nano /etc/sysconfig/network-scripts/ifcfg-eth0

Should look something like this


DEVICE=eth0
BOOTPROTO=static
BROADCAST=172.16.0.255
HWADDR=00:00:00:00:00:00
IPADDR=172.16.0.2
NETMASK=255.255.255.0
NETWORK=172.16.0.0
ONBOOT=yes

Duplicate that and open the new file

cp /etc/sysconfig/network-scripts/ifcfg-eth0 /etc/sysconfig/network-scripts/ifcfg-eth0:0
nano /etc/sysconfig/network-scripts/ifcfg-eth0:0

Change device name, set new IP, remove reference to hardware


DEVICE=eth0:0
BOOTPROTO=static
BROADCAST=172.16.0.255
IPADDR=172.16.0.3
NETMASK=255.255.255.0
NETWORK=172.16.0.0
ONBOOT=yes